Technology: Other surface modification technologiesPTA process

The PTA process overlay welding employs filler materials in powder form, including ceramics and other super hard materials that are unable to be processed into wire or rod form.

A coating with optimal properties is produced by compounding various metal alloy powders and ceramic powders and controlling their mix proportion. The welded surface can then be finished with cermet.

The coating also offers excellent peeling resistance due to the metallic bond formed between the coating and the base metal.

Overlay welding also facilitates the creation of thicker coatings compared to other coating methods.

The high hardness at high temperatures and superb wear, burning, and corrosion resistance give PTA coating potential for applications in various industries.

PTA process

Overlay welding by PTA

Principle of PTA

Figure 1 shows the PTA overlay welding mechanism. First, a pilot power supply is used to produce an electric arc, which is carried to argon gas flow between a tungsten electrode and a water-cooled nozzle. The argon gas transforms into plasma, and the hot plasma gas converges under the thermal pinch effect of the water-cooled nozzle to flow to the substrate as a high-energy plasma arc. When the arc reaches the substrate, the main power is supplied to maintain the status, and the arc current flows to the substrate where it forms a molten pool on the surface. At the same time, the welding-powder material is force-fed into the plasma arc by a carrier gas such as helium or argon. The material melts and is infused to the molten pool on the base metal surface to form the overlay layer.

Figure 2 compares the temperature distribution of the convergence of plasma arc and the TIG arc. The water-cooled nozzle intensively compresses the plasma arc and creates high-energy density, thus enabling powder with high melting points to be used as the filler material.

Principle of PTA(1)
Principle of PTA(2)

Main alloy powders employed

Stainless steels SUS309, SUS316, SUS316L, SUS410, etc.
Nickel alloys Inconel 625, 50Ni-50Cr, Hastelloy, Colmonoy #5, etc.
Stellites #1, #6, #12, #20, #21, etc.
Others High speed steel, Tribaloy, special heat-proof alloy, etc.

Main carbide powders used

Carbide/
properties
Melting point (K) Density (Mg/m3 Hardness
Micro Vickers
Thermal expansion coefficient
(10-6K-1)295–1273K
Electric resistivity
(10-6Ω•m)
TiC 3,453–3,523 4.85–4.93 2,900–3,473 7.95 0.70–1.73
VC 3,083–3,138 5.36–5.77 2,800 7.25 1.5–1.6
NbC 3,773–4,073 7.82 2,400 7.21 0.74–2.54
Cr3C2 2,168 6.68 1,800 11.7(293–1,373K) 0.70–0.80
W2C 3,123 17.2 3,000 6.0 0.80
WC 2,900–3,173 15.6–15.7 2,400 3.84 0.53

Section macrostructures of overlaid alloy with various carbide particles dispersing in it

Section macrostructures of overlaid alloy with various carbide particles dispersing in it

SEM structure of overlaid alloy with various carbide particles dispersing in it

SEM structure of overlaid alloy with various carbide particles dispersing in it

PTA process flow

PTA process flow